SECTION 1 – PRODUCT AND COMPANY IDENTIFICATION

Section 2 – Hazards Identification

2.1 Classification of the substance or mixture:

Mixture is classified as hazardous in according with regulation EC 1272/200. 

Flam. Liq. 3, H226 – Flammable liquid, category 3: Flammable liquid and vapour

Skin Sens H317 – Skin sensitisation, category 1: May cause an allergic skin reaction 

Eye Irrit. 2, H319 – Eye Irritation, category 2: Causes serious eye irritation. 

2.2 Label elements : 

Mixture label and phrases designing the conditions of safe use with the regulation (EC) no. 1272/2008

Signal word: WARNING 

Hazardous statement: 

H226 : Flammable liquid and vapour

H317 : May cause an allergic skin reaction

H319 : Causes serious eye irritation 

Precautionary statement: 

P102 : Keep out of reach of children

P210 : Keep away from heat, hot surfaces, sparks, open flames and other ignition sources

           No smoking

P280  :  Wear protective gloves/eye protection

P333+ P313 : If skin irritation or rash occurs: Get medical advice/attention

P337+ P313 : If eye irritation persists get medical advice/attention.

P501 : Dispose of contents/container to places designed for the storage of the dangerous    

ySubstance or pass to services who deal with waste utilization

Section 3 – Composition/Information on Ingredients

Section 4 – First Aid Measures

4.1 Description

Section 5 – Fire Fighting Measures

5.1 Extinguishing measures:

Suitable extinguishing measures: extinguishing powders, extinguishing foams, CO2

Unsuitable extinguishing measures: compact water flow

5.2 Special hazards arising from the substance or mixture

If burning , may produce hazardous fumes or vapors: carbon dioxide/nitric oxide/ carbon monoxide.

5.3 Advice for firefighters

Firefighters should have special protective equipment such as: clothes, coveralls, gloves, eyes and face protective equipment and respiratory device. Container exposed on fire or high temperature cool, pouring water and if possible remove from endangered area.

Section 6 – Accidental Release Measures

6.1 Personal precautions, protective equipment and emergency procedures:

Ensure appropriate ventilation. Use protective clothes and all security measures to avoid the contact of the substance with the skin and eyes.

6.2 Environmental precautions

Secure gullies from getting the mixture into sewage system, surface water & ground water. Place little capacities of the mixture on the absorbing mats. In case of a transport use absorbing baths.

6.3 Methods and materials preventing the contamination and cleaning up

In case of contamination of the mixture save sewage  system from further leaks by embanking or the use of absorbing materials (sand, diatomaceous earth, sawdust, binders) or remove to closed containers. Secure damaged containers. A dollop of mixture rinse with plenty of water. The place of contamination wash with detergents.

6.4 Reference to other sections

See section 8 and 13

Section 7 – Handling and Storage

Section 8 – Exposure Controls / Personal Protection

8.1 Control Parameters

Legal basis: COMMISSION DIRECTIVE: 2000/39/EC, 2006/15/EC, 2009/161/EU

Please check any national occupational exposure limit value for components in your country from Section 3.

8.2 Exposure control

Technical guidance:

Ensure adequate ventilation and places to wash the eyes, hands and the storage protective clothes (hangers, wardrobes) place for the working time and after its end.

Personal protection:

All protections should be chosen to at least one substance on a highest per cent concentration in the mixture.

Respiratory protection:

In the normal conditions of the mixture use, it is not necessary to use additional protection. In case when is likely an appearance of vapor one should use ventilation to remove contaminated air from work place. With too little efficiency of the ventilation you can use half-masks with absorbers A type (brown colour) or AX (brown colour) or SX (violet colour) on a 1 class protection. Mask should the most precisely adhere to the face. Every half-mask should met the norm EN 140:2001, absorbers norm EN 14387: 2006 or newer.

Skin protection:

a)Protective gloves made in a whole of gum or plastic may be additionally knurled on the absorbing resistance on the 3 level. Gloves should be adjusted individually to every worker, not hindering the work. Taking off to avoid the skin contamination. Gloves should meet the norm EN 374-1:2005 or newer.

b)While working with the mixture use at least a front smock protecting against chemical substances, meeting the norm EN 14605, use additionally antyelectrostatic clothes.

c)In case of transport of a substantial amount of the mixture you may use protective shoes, chemical resistant II category according to the norm EN 13832-2007 or newer, with the time absorption 3.

Eyes or face protection:

In case of possibility of splashing the mixture you can use protective goggles, adhering closey to the face of a user. Familiarize with producer’s info before use. Goggles should meet the norm EN 166.

Before work with protective clothes or equipment, watch them carefully, look after the date of use. If they will lose their properties during the work, change them immediately to new ones. Read carefully the information enclosed to clothes or equipment.

The final decision about using protective clothes should be undertake after familiarizing with work conditions, taken along with Health and Safety worker.

Section 9 – Physical And Chemical Properties

9.1 Information on basic physical and chemical properties

Section 10 – Stability & Reactivity

10.1 Reactivity

Little reactive mixture. It is not polymerized.

10.2 Chemical stability

Stored and used in recommended conditions is stable.

10.3 Possibility of hazardous reactions

Hazardous reactions are not known.

10.4 Conditions to avoid

Avoid sunlight, keep away from the source of heat and fire damp places

10.5 Incompatible materials

Strong oxidian substances.

10.6 Hazardous decomposition products

Not known

Section 11 – Toxological Information

11.1 Information on toxological effects

There is not available data concerning the toxicity for the mixture.

Section 12  – Ecological Information

The impact of the mixture is impossible to establish empirically. It is advised to use all the possible ways not to release to the environment.

12.1 Toxicity

There is not available data concerning the toxicity for the mixture.

12.2 Persistence and degradability

There is not available data for the mixture concerning degradability in the environment by biodegradation or other processes.

12.3 Bio-accumulative potential

There is not available data concerning bioaccumulation for the mixture.

12.4 Mobility in soil

There is not available data concerning mobility in soil for the mixture.

12.5 Results of PBT and vPvB

No data available.

12.6 Other adverse effects

There is not available data concerning other adverse effects.

Section 13 – Disposal Considerations

Waste treatment methods: 

Store mixture in original containers. Do not pour into sewage. Reuse in accordance with the local legislation. 

Recycle or Reuse or liquidate empty containers in accordance with local legislation.

Disposal method can be found in the directive of European Parliament and Council: 2008/98/EC, 94/62/EC

Section 14 – Transportation Information

UN number

ADR/RID/ICAO: 1197

UN proper shipping name

ADR/RID/ICAO: ICAO: Extracts, Flavoring, Liquid

Transport hazard class (es)

ADR/RID/ICAO: 3

Packaging group

ADR/RID/ICAO: III

Environmental hazards

ADR/RID/ICAO: No

Special precautions for the users

Use personal protective equipment as recommended by ADR/RID/ICAO

Transport in bulk in accordance to Annexe II of MARPOL 73/78 & IBC Code

Section 15 – Regulatory Information

15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture

-Regulation (EC) no 1907/2006 of the European Parliament and of the Council of 18 December 2006 concerning the Registration, Evaluation, authorization and Restriction of Chemicals (REACH), establishing a European Chemicals Agency, amending Directive 1999/45/EC and repealing Council Regulation (EEC) no 793/93 and Commission regulation (EC) no 1488/94 as well as Council Directive 76/769/EEC and Commission Directives 91/155/EEC/ 93/67/EEC, 93/105/EC and 200/21/EC

-Regulation (EC) no 1272/2008 of European Parliament and of the Council of 16 December 2008 on classification, labeling and packaging of substances and mixtures, amending and repealing Directives 67/548/EEC and 1999/45/EC, and amending Regulation (EC) no 1907/2006

– Commission regulation (EC) no 790/2009 of 10 August 2009 amending, for the purposes of its adaption to technical and scientific progress, regulation (EC) no 1272/2008 of the Indian Parliament & of the Council on classification, labeling and packaging of substances & mixtures

– Commission regulation (EU) no 830/2015 of 28 May 2015 amending regulation (EC) no 1927/2006 of the European Parliament and of the council on the Registration, evaluation, Authorization and Restriction of Chemicals (REACH)

– Directive of the Council no 86/686/EEC of 21 December 1989 on the rapprochement of the legislation of members state concerning personal protective equipment

15.2 Chemical safety assessment 

Not required chemical safety assessment for the mixture

Section 16 – Other Information

The information contained in this safety data sheet is intended to describe only terms of safety requirements. A user is responsible for taking all necessary steps for the requirements of national law and to create conditions for safety use of the product. The user takes full responsibility for the consequences of the use of this product. 

Classification of the mixture on the grounds of total hazardous substances, inflammability basis on measurement 

Explanation of abbreviations and acronyms: 

ADR – European agreement concerning international road transport of hazardous goods Aquatic Chronic. – Chronic hazardous to the aquatic environment 

CAS – Numerical notion designed to a chemical substance by Chemical Abstract Service 

ICAO – International Civil Aviation Organisation 

PBT – Stable substances, toxic and having capacity to bioaccumulation

RID – Rules of international rail transport of hazardous goods 

EC –designs the number assigned to a chemical substance in European List of Commercial  

       Existing Substances 

vPvB -Very stable substances, having very big capacity to bioaccumulation 

H-phrases mentioned in section 3: 

H226    :  flammable liquid and vapour 

H302    :  Harmful is swallowed

H317    :  May cause an allergic skin reaction

H319    :  Causes serious eye irritation

H411    :  Toxic to aquatic life with long lasting effects 

2.3 Other hazards

In the content of the mixture does not consist PBT or vPvb substances or affecting the ozone layer.

Full text of showing type of hazard H is given in section 16.

4.2 Most important symptoms and effects, both acute and delayed

In case of a contact of the mixture with the skin possible are skin redresses and irritations. In case of eye contact redness if possible. In case of ingestion irritations of digestive track are possible with vomiting and nauseas. Prolonged symptoms require an immediate medical help. If needed show label/product leaflet.

7.1 Precautions for safe handling

Mixture should be used in a well ventilated rooms far away from the sources of heat and ignition and electric wires. Do not inhale vapors. It is advised to take  safety precautions to avoid the skin and eye contact of the mixture. Do not eat, drink, smoke in a work place. After work or in case of leaving the work place wash hands carefully and take off the workwear.

7.2 Conditions for safe storage, including any incompabilities

Protect from the sunshine’s. Keep in a dry, ventilated, dark place, in the temperature 5-25oC away from heating sources in tightly closed, original boxes.

7.3 Specific end uses

Aromatizing composition

9.2 Other  information

No additional data